Heat-sensitive two color recording paper

ABSTRACT

1. A HEAT-SENSITIVE TWO COLOR RECORDING PAPER WHICH HAS A LAYER OF A FIRST HEAT-SENSITIVE RECORDING MATERIAL PREPARED BY DISPERSING, AS DISCONTINUOUS PARTICLES INTO A FILMFORMING BINDER, A TRIPHENYLMETHANE OR FLUORAN TYPE NONCOLORED DYE BASE HAVING IN THE MOLECULE A REACTIVE COLORDEVELOPING COMPONENT OF THE LACTONE OR LACTAM TYPE, AND A PHENOLIC SUBSTANCE OR AN ORGANIC ACID, SAID LAYER DEVELOPING A COLOR AT THE TIME OF APPLICATION OF HEAT, BY FORMATION OF A COLOR-DEVELOPING SUBSTANCE, AND A LAYER OF A SECOND HEAT-SENSITIVE RECORDING MATERIAL CA VELOPING AT THE SAME TIME OF APPLICATION OF HEAT A COLOR DIFFERENT FROM THE COLOR OF THE AFORESAID FIRST LAYER, AND WHICH CONTAINS AS A DECOLORIZING AGENT FOR THE COLOR-DEVELOPING SUBSTANCE CONTAINED IN THE FIRST LAYER A THERMOFUSIBLE POLYETHER WHICH IS SUBSTANTIALLY SOLID AT NORMAL TEMPERATURE.

Oct. 22, 1974 KINICHI ADACHI ETAL 3,843,384

HEAT-SENSITIVE TWO COLOR RECORDING PAPER Filed June 12, 1972 6 Sheets-Sheet 2 KINICH ADACHI ETAL' 3,843,384

HEAT-SENSITIVE TWO COLOR RECORDING PAPER Oct. 22, 1974 6 Sheets-Sheet 5 Filed June 1972 FIG.6

Ewzwa #650 mzBwHmm TEMPERATURE, (0)

Oct. 22, 1974 KlNlCHI ADACH! ETAL HEAT-SENSITIVE TWO COLOR RECORDING PAPER Filed June 12, 1972 6 Sheets-Sheet 4.

FIG. 7

THERMAL HEAD APPLYING POWER (mi/pulse) d. 22, 1974 I KIN|CH| ADACH! ETAL 3,843,384

HEAT'SENSITIVE TWO COLOR RECORDING PAPER Filed June 12. 1972 I 6 Sheets-Sheet FIG. 8

REFLECTIVE OPTICAL DENSITY 0 I I I 80 [0Q I I40 I TEMPERATURE (C) Oct. 22, 1974 K|N|CH| ADACH| ETAL. 3,843,384

HEAT-SENSITIVE TWO COLOR RECORDING PAPER 6 Sheets-Sheet 6 Filed June 12, 1972 It) O f Y AllSNBCI 'TVOLldO HNlOEHdBH am 6E mdi AlISNBC] "IVOLLdO HAliOHl-BH United States Patent 3,843,384 HEAT-SENSITIVE 'II'L VXOPE(II{OLOR RECORDING Kinichi Adachi, Takarazuka, and Takeshi Takaoka, Katano, Japan, assignors to Matsushita Electric Industrial Co., Ltd., Osaka, Japan Filed June 12, 1972, Ser. No. 261,969 Claims priority, application Japan, June 14, 1971, 46/42,341; Aug. 5, 1971, 46/59,395; Aug. 10, 1971, 46/60,752; Aug. 20, 1971, 46/63,815

Int. Cl. B41m /18 US. Cl. 117--36.9 13 Claims ABSTRACT OF THE DISCLOSURE A heat-sensitive two color recording paper having first and second layers which individually develop different colors due to difference in quantity of heat applied to the paper surface, in which the color-developing component of the first layer is composed of (i) a triphenylmethane or fluoran type dye base having in the molecule a reactive color-developing component of the lactone or lactam type and (ii) a phenolic substance or an organic acid. This recording paper contains polyether as a decolorizing agent for removing the color developed in the first layer, and the color of the first layer is removed at the time when the second layer develops a color, so that a clear two-colored record can be obtained.

This invention relates to heat-sensitive recording materials for use in information terminal machines such as, for example, facsimile, telegraphic machines, telewriters, electronic computers, various measuring machines and copying machines.

Recording materials which have heretofore been used in the above-mentioned machines are represented by conventional photographic materials, electrophotographic materials, electrostatic recording papers, electrolytic recording materials, diazo papers, etc. All these recording materials, however, require toners or developer and fixer at the image-forming step, so that the cleaning of recording machines and the supply of chemicals have been indispensable. Further, inks are used in the recording machines available at present, so that there have been such inconveniences from the standpoint of users that recording papers are stained with the inks, or solids formed due to vaporization of solvents used in the inks clog the inkdischarging holes of pens, with the result that figures to be recorded become thin or, in extreme cases, cannot be recorded. In order to overcome the above-mentioned drawbacks, many pressure-sensitive recording materials have come to be used. At present, however, the said recording materials are used as copying papers or teletyping papers in place of carbon papers, and thus are limited in uses.

On the other hand, many types of heat-sensitive recording materials have heretofore been proposed. Among these recording materials, those which have already been put into practical use or which will be practically used in the near future are as follows:

1) A heat-sensitive sheet prepared by uniformly applying carbon or the like coloring pigment or dye powder onto a substrate, and coating on the resulting color layer a white and opaque thermofusible substance. This sheet is of such a type that the thermofusible substance on the surface is scribed with a thermal pen to expose the lower color layer. A recording material of this type has such drawbacks that wastes are formed and multi-color recording is impossible.

(2) A recording material of such a type that a color is formed by the formation of a complex compound of an electron donor with an electron acceptor. For example,

ferric s tearate and pyrogallol are independently dispersed in a binder, and the thus treated binder is softened by application of heat, whereby the two compounds react with each other to form a complex compound which forms a color. The color developed in this case is dark brown.

(3) A recording material of such a type that Crystal Viiolet Lactone and a phenolic substance are dispersed as discontinuous particles into a thermoplastic substance such as polyvinyl alcohol or the like, and the binder is softened by application of heat. The color developed in this case is cobalt blue. While this type suggests a promising way of heat-sensitive recording materials, there is a problem in how to obtain a record having 2 or more colors.

As mentioned above, recording materials for terminal machines should satisfy such conditions that they can. give clear records without any substantial trouble from the recording machines employed. In this respect, the heatsensitive material of the above-mentioned type (3) is a preferable material, since it gives a clear image by mere application of a thermal head. However, high density informations have come to be required with the progress of society, and the demand for records having 2 or more colors is strong.

With an aim to satisfy the above demand, the present inventors made studies on the conventional heat-sensitive recording materials of this kind to find a heat-sensitive recording paper capable of forming clear two colors.

It is therefore an object of the present invention to provide a recording paper which develops, for example, a red color when recording is made by use of a thermal pen (or a thermal head) kept at a certain temperature, and which further develops, for example, a blue color when recording is made by use of a thermal pen kept at a higher temperature.

In the accompanying drawings, FIGS. 1 to 2 diagrammatically show the cross-sections of several recording papers of the present invention and FIGS. 4 and 5 show the cross-sections of recording papers for reference; FIGS. 6 and 8 are individually a color development sensitivity curve showing the relation between temperature and reflective optical density; FIG. 7 is a graph showing the relation between thermal head applying power and reflective optical density; and FIG. 9 is a graph showing the relation between width of line and reflective optical density.

As seen in FIG. 1 for example, the recording paper of the present invention is composed of a first heatsensitive recording material layer 1 which develops a color by the reaction of a triphenylmethane or fluoran type dye base (hereinafter referred to as color-forming dye) having in the molecule a reactive color-developing component of the lactone or lactam type with a phenolic substance or an organic acid (hereinafter referred to as color-forming agent); a second heat-sensitive recording material layer 2 which develops a color by the reaction of a diazo compound with an azo coupler; a layer 3 disposed between the said two layers 1 and 2 which contains a decolorizing agent for removing the color of the color-forming substance contained in the first layer 1; and a substrate 4. In FIG. 1 4 is a recording thermal head. In the first layer, the color-forming dye 11 and the color-forming agent 12 have independently been dispersed as discontinuous particles into a film-forming binder 13, which is solid at normal temperature but is softened when heat is applied thereto. Accordingly, when the binder is heated by applying a certain quantity of heat to the surface of the recording material, the color-forming dye reacts with the color-forming agent to develop a color. In the second layer, the diazo compound 21 and the azo coupler 22 have independently been dispersed as discontinuous particles into a film-forming binder 23, which is solid at normal temperature but is softened when heat is applied thereto. Accordingly, when the said binder is heated by applying a certain quantity of heat to the surface of the recording paper, the two compounds react with each other to develop a color different from the color of the first layer.

The recording materials constituting the above-mentioned first and second layers have individually been known as heat-sensitive recording materials of this kind. However, the recording paper of the present invention is characterized in that a thermofusible polyether is used as the decolorizing agent for the color-developing substance of the first layer. In the case of the recording paper of the present invention, therefore, the quantity of heat (hereinafter referred to as heat A) necessary to develop the color of the first layer and the quantity of heat (hereinafter referred to as heat B) necessary to develop the color of the second layer are in such a relation as to satisfy the inequality A B. Further, the said decolorization agent is substantially solid at normal temperature, but is fused and fluidized when the heat B is applied to the paper surface. That is, when the quantity of heat applied to the paper surface in order to fiuidize the decoloring agent is deemed as heat C, the heats A, B and C are in such a relation as to satisfy the inequality A CB.

The quantities of heat applied to these layers 1, 2 and 3 are dependent on the temperature of the recording thermal head 5 to be contacted with the paper surface, the time of contact of the thermal head with the paper surface, and the thermal conductivity of the paper from the surface of each layer. For example, in the case of the recording paper of such a construction as shown in FIG. 1, the quantity of heat applied to the first layer 1 is greater than the quantity of heat applied to the second layer 2, even though the temperature of the thermal head and the time of contact of thermal head with the paper surface are definite. In the above case, the temperature of the first layer is higher than that of the second layer. Accordingly, the color forming temperature of the second layer is not always required to be higher than that of the first layer. Generally, however, the color forming temperature of the second layer is made higher than that of the first layer.

The color formation mechanism of the first layer and the mechanism of removing the color formed in the first layer with the polyether in the inter layer are explained below.

The fact that a leuco dye base of the triphenylmethane type such as Crystal Violet Lactone forms a color by reaction with a phenolic substance such as phenol or cresol or with an inorganic or organic acid has been clarified by 0. Fischer et a1. [Berichte der Deutschen Chemischen Gesellschaft, 42, 2934-2935 (1909)]. Further, a leuco dye base of the fluoran type also shows the same property as above. It is said that the mechanism of the above-mentioned reaction is such that the electron attractive acid attracts the electrons of amine of the dye base, whereby the dye base is ionized to form a color. When the abovementioned kind of color-forming dye and color-forming agent are contacted with each other, they react in the above manner to form a color. In this case, either one or both of the color-forming dye and color-forming agent may be dissolved in a thermoplastic substance such as polyvinyl alcohol or the like.

Since the above-mentioned color-forming dye forms a color due to such ionization as mentioned above, no color is formed in the presence of a polar solvent or the like substance which disturbs the ionization. In the present invention, the fact that the color-forming dye brings about no color formation reaction in the presence of a polyether is utilized, so that in case the second layer is desired to be made visible, the color formed in the first layer is removed by the polyether to make the second layer clearly visible. Concretely, the first heat-sensitive recording material layer shown in FIG. 1, which has developed a color by the reaction of a leuco dye base of the triphenylmethane or fluoran type with a phenolic substance or an organic acid, is decolored by a polyether or the like substance, as explained above. Accordingly, the recording paper of such a construction as shown in FIG. 1 can develop two brilliant colors by varying the quantity of heat applied.

The recording paper of the present invention is such that in forming the color of the second layer, the color formed in the first layer is removed by means of the polyether, as mentioned above, to obtain a color which has not been migrated with the color of the first layer. Accordingly, the color forming reaction of the second layer should not be affected by the polyether.

In the case of the recording paper shown in FIG. 1, the combination of a diazo compound and an azo coupler is used as the color-forming component of the second layer. When heat is applied to the recording paper, the film-forming binder, which separates the said two components from each other, is softened, with the result that the two components contact with each other and bring about a coupling reaction to form a color. Accordingly, the second layer is different in color forming mechanism from the first layer which forms a color due to ionization of dye base, and the color forming reaction of the second layer is not affected at all by the polyether.

As components which are not afiected by polyether and usable as color-forming components of the second layer, there are combinations of electron acceptors and electron donors, in addition to the combination mentioned above.

Alternatively, the recording paper of the present invention may have such a construction as shown in FIG. 3. That is, the second layer 2 is a previously colored layer, and the inter layer 3 is composed of a thermoplastic polymer or wax 32, which itself can form a transparent thin layer, and a polyether 31 as the decolorizing agent. The said polyether has been dispersed as particles into said polymer or wax so as to form a dispersed layer, and the thus formed inter layer 3 has been used to cover the colored layer, i.e. the second layer 2. At the time of developing the color of the second layer 2, the inter layer 3 is fused by application of heat so that the color image formed in the first layer is decolored by the polyether and, at the same time, the second layer is made visible.

Further, as the color-forming component of the second layer 2, there may be used, like in the case of the first layer 1, a triphenylmethane or fluoran type dye base having in the molecule a reactive color-forming component of the lactone or lactam type. In this case, however, the color of the second layer is also removed by the polyether, so that the amount of the color-developing substance in the second layer should be made larger than that in the first layer. The amount of the colordeveloping substance in the second layer is at least 5 parts by weight per part by weight of the color forming substance in the first layer. When the above-mentioned amount is employed, the second layer can sufi'iciently develop a clear color even when the polyether is used in an amount sufficient to remove the color of the first layer. In case such procedure is adopted, it is desirable to bring the recording paper into such a construction that the inter layer 3 is incorporated with the polyether and is disposed between the first and second layers, as shown in FIG. 1.

As to the polyether as the decolorizing agent, FIG. 1 shows the case where the inter layer 3, which has been formed by dispersing particles of the polyether 31 in the thermoplastic binder 32 is disposed between the first and second layers. As shown in FIG. 2, however, it is also possible that the inter layer 3 is omitted, and. the. polyether 31 is dispersed in the second layer 2.

1. First heat-sensitive recording material It has already been clarified that a leuco dye of the triphenylmethane type such as Crystal Violet Lactone develops a brilliant color by reaction with clay, an inorganic acid, a phenolic substance or an organic acid. In order to apply such color-forming phenomenon to reocrding, there has been adopted a process in which a leuco compound of dye and a phenolic substance or an organic acid are independently dispersed in a physical manner into a binder. Further, it has been found that a dye base of the fluoran type is effectively usable in the present invention as a novel color-forming agent.

(a) Colorforming dye: Generally, a triphenylmethane type leuco dye base represented by the formula (I) shown below or a fluoran type dye base represented by the formula (II) shown below is used.

R Rx Z Ry wherein R R and R are individually a hydrogen atom, a hydroxy group, a halogen atom, an alkyl group, a nitro group, an amino group, a dialkylamino group, a monoalkylamino group or an aryl group; and Z is an oxygen or sulfur atom necessary to form a heterocyclic group.

Typical examples of the above-mentioned compound are as follows:

Compounds of the formula (I):

3,3-Bis(p-dimethylaminophenyl)-phthalide 3,3-Bis (p-dimethylaminophenyl -6-dimethylaminophthalide [Crystal Violet Lactone] 3,3-Bis (p-dirnethylaminophenyl) -6-nitrophthalide 3,3-Bis( (p-dimethylarninophenyl) -6-monomethylaminophthalide 3,3-Bis(p-dimethylaminophenyl)-6-chloropht halide 3,3-Bis-(p-dimethylaminophenyl)-6-ethoxyphthalide 3,3-Bis (p-dimethylaminophenyl) -6-diethylaminophthalide Compounds of the formula (II):

3-Dimethylamino-G-methoxyfluoran 7 -Acetamino-3-dimethylaminofiuoran 3-Dimethylamino-5,7-dimethylfluoran 3-Diethylamino-5,7-dimethylfluoran 3,6-Bis-,8-methoxyethoxyfluoran 3,6-Bis-B-cyanoethoxyfluoran Other lactam compounds:

9-p-Nitro anilino-3 6 -bis diethylamino -9-xanthenylfi-benzoic acid lactam [Rhodamine lactam] 9-Nitroamino-3 ,6-bis (dimethylarnino) -9-thioxanthenyl- 6-benzoic acid lactam is solid at normal temperature and melts or gasifies at above 50 C. Examples of such phenolic substance and organic acid are as follows:

( 1) Phenolic substances:

(2) Organic acids:

p-Hydroxybenzoic acid m-Hydroxybenzoic acid o-Hydroxybenzoic acid Boric acid Tartaric acid Oxalic acid Maleic acid Citric acid Succinic acid Gallic acid l-Hydroxy-Z-naphthenic acid Z-Hydroxy-p-toluyl acid (c) Binder: When a dispersion formed by merely dispersing the aforesaid color-forming dye and color-forming agent in water or in a non-polar or slightly polar organic solvent is coated on a substrate, the resulting recording paper becomes high in fog or suffers from peeling and thus is low in practicality. It is therefore necessary to use a binder which can disperse and fix said color-forming dye and color-forming agent as discontinuous particles at normal temperature. Due to its inherent property, the binder is softened or melted when heat is applied thereto, whereby the formation of dye is promoted. Examples of such binder are as follows:

(1) Water-soluble binders:

Polyvinyl alcohol Methoxycellulose Polyacrylic acid Polyvinyl pyrrolidone Hydroxyethyl cellulose Gelatin Polyacrylamide Starch Carboxymethyl cellulose These are preferable binders which are dissolved in or swelled with water to provide tackiness.

(2) Binders soluble in non-polar or slightly polar organic solvents:

Natural rubber Synthetic rubbers Styrene-butadiene copolymers Chlorinated rubbers Polybutyl methacrylate These binders disperse and fix the aforesaid color-forming dyes and color-forming agents as discontinuous particles at temperatures below the heat recording temperature and, at the same time, play the role of adhering them to substrates. It is desirable to use a binder which is not easily discolored by heat.

(d) Other additives: In order to enhance the recording paper in whiteness and printability and to prevent the adhesion of thermal head, there may be used talc, titanium oxide, zinc oxide, calcium carbonate or the like. Further, in order to carry out the formation of dye at a sharp temperature, there may be used urea, thiourea, acetanilide, phthalic anhydride or the like thermofusible substance Alkyl resins which can melt the aforesaid color-forming dye and color-forming agent at the time of melting.

2. Decolorizing agent It is said that the formation mechanism of a color by use of the aforesaid color-forming agent and colorforming dye is such that an electron attractive acid attracts the electrons of amine of a dye base, thereby bringing about the ionization of the dye base. Accordingly, no color is developed in the presence of a polar solvent or the like substance which disturbs the ionization of dye base. The present invention utilizes the fact that a substance, which has developed a color by use of the said color-forming dye and color-forming agent, is decolored in the presence of a polyether.

A polyether having such decolorizing efiect is represented by the general formula,

tM-Oix wherein x is an integer of 1 or more, and M is a methylene or polymethylene group or a derivative thereof.

Typical examples of such polyether are as follows:

( 1) Polyoxydecamethylene (2) Polyoxymethylene (3) Polyethylene oxide (4) Trimethylene oxide polymers (5) 1,3-Dioxolan polymers (6) Alkylamine type cationic surface active agents represented by the following general formulas:

wherein R and R are individually a fatty acid chain, and

x and y are individually an integer of 1 or more.

Polyethylene glycol type nonionic surface active agents represented by the following general formulas:

0 R-C-O-(CHrCHzOhH Ester type R--oomcmo .n Alkylphenol type (H) )0 HzCH20 nH RCN\ Polyhydric alcohol partial ester type CH CH O mH H2O CHCHzO 0 O R Sorbitol type 11011 HOH fatty acid esters L IOH wherein R is a fatty acid chain, and n and m are individually an integer of 1 or more.

Typical examples of the above-mentioned polyethers are as follows:

In addition to the above-mentioned decolorizing agents, compounds having the skeleton in the molecules can be used as decolorizing agents in the present invention.

It is desirable that the binders are solid at normal temperature. According to the capsulating technique at present, however, binders in the form of liquids may also be successfully used so far as the wall materials of capsules are suitably selected.

3. Second heat-sensitive recording material The first heat-sensitive recording material is decolorized with a decolorizer, but the second heat-sensitive recording material should not be decolorized with a decolorizer. It is therefore desirable that the second color-forming layer is composed of a substance which develops a color by application of heat larger in quantity than the heat required for decolorizing the first layer. Preferable examples of the above-mentioned substance are such combinations of electron acceptors and electron donors as mentioned below.

Electron acceptor Electron donor (1).- Metal salts of long chain Phenols (e.g., ammonium salts of fatty acids (e.g., ferric tannic, gallic and salicylic stearate and ferric acids).

myristate).

(2). Heavy metal salts of organic acids (e.g., Ni, Co, Pb, Cu, Fe, Hg and Ag salts of acetic, stearic and palmitic acids).

(3). Organic chelates (e.g., thio- Sulfur compounds (e.g., sodium diphenyl carbazide and tetrathionate, sodium thiosuli'ate diphenyl carbazone). and thiourea).

(4). Heavy metal salts of oxalic Sulfur compounds (e.g., sodium acid (e.g., Ag, Pb, Hg tetrathionate, sodium thiosultate and Th salts). and thiourea).

(5). Noble metal salts of organic Organo-polyhydroxy compounds acids (e.g., silver oxalate (e.g., polyhydroxy alcohol, and mercury oxalate). glycerin and glycol).

(6).. Noble metal salts of organic Aromatic organic reducing agents acids (e.g., silver behenate (e.g., protocatechuic acid, spiroand silver stearate). indane and hydroquinone).

(7) Aliphatic ferric salts (e.g., Aromatic polyhydroxy compounds ferric stearate) (e.g., %4-dihydroxy tetraphenyl m ane).

(8)- Metal salts of organic acids Cyclic organic reducing agents (e.g., silver behenate and (e.g., protocatechuic acid and acidic silver phthalate). 2,3-dihydroxy-benzoic acid).

(9). Lead salts of organic acids Thiourea derivatives (e.g.,

(e.g., lead caproate and ethylene thiourea and N-dodecyl lead behenate). thiourea).

(l0) Grignard type organo- Sulfur compounds.

metallic compounds.

Alkaline earth metal salts (e.g.,

CaS, SrS and BaS).

Alternatively, the second heat-sensitive recording material is composed mainly of at least one compound selected from diazo compounds and azo type diazo compounds, an azo coupler and a binder.

(a) Diazo compounds and azo type diazo compounds: It is desirable that these compounds are stable to light and is slightly colored or white or colorless.

(1) Diazobenzenes having the substituents m-CH p- Cl, p-Ph, p-NO m-NO o-Cl, 0-CH and p-N=N-Ph, wherein m, p and 0 before the substituents represent the positions of substitution, and Ph represents a phenyl group.

Examples of the above compounds are as follows:

1-Daizo-2-nitro-4-chlorobenzene-% ZnCl 1-Diazo-2-methyl-4-chlorobenzene-% ZnCl 1-Diazo-2-chlorobenzene-% ZnCl (2) A20 type diazo compounds:

4-Amino-3-nitroanisole hydrochloride-V2 ZnCl o-Nitroaniline-ZnCl 4-Chloro-2-nitroaniline -ZnCl Stable diazonium compounds of 4-chloro-2-trifluoromethylaniline Stable diazonium compounds of 2,6-dichloro-p-phenylenediamine p-Nitroaniline 3-Hydroxy-2-naphthanilide 3-Hydroxy-2-naphtho-o-toluidide 3-Hydroxy-2-naphtho-2-ethoxyanilide 3-Hydroxy-2-naphtho-o-anisidide 1,3,5-Hydroxybenzene 3,5-Diethoxyphenol 3-Acetamidophenol 1,3,5-Resorcyclic acid anilide 4,4,6,6'-Tetrahydroxyphenyl l-Hydroxynaphthalene 2-Hydr0xynaphthalene-4-sulfonic acid 2-Hydroxynaphthalene-3,6-disulf0nic acid 2-Hydroxy-2-naphthoic acid diethanolamide 5,5'-Dimethyl-1,3-cyclohexanedione Cyanoacetanilide 3-Hydroxy-2-naphthoic acid-3-morpholino propylamide (c) Binders: Since azo dye-forming components comprising the aforesaid diazo compounds or azo type diazo compounds and azo couplers are water soluble, it is preferable to use binders which are soluble in non-polar or slightly polar organic solvents. Examples of such binders include natural rubber, synthetic rubbers, chlorinated rubbers, alkyd resins, polystyrene, styrene-butadiene copolymers, polymethyl methacrylate, ethyl cellulose, nitrocellulose and polyvinyl carbazole.

(d) Other additives: Additives are used in order to prolong the second heat-sensitive recording material in life and to make brilliant the thermally formed colors. For example, a basic substance such as ammonium carbonate, ammonium salicylate, urea, thiourea or amine takes part in the thermal color-forming of the material, and an organic acid such as palmitic acid, stearic acid, hydroquinone, resorcinol, salicylic acid, tartaric acid, citric acid or p-hydroxybenzoic acid, or a phenolic acid has etfect of enhancing the material in storage stability.

It is also possible to bring the recording paper of the present invention to such a construction that the second layer is composed of a colored layer and the inter layer, which covers the second layer, is composed of a lightscattering layer in which has been dispersed the aforesaid decolorizing agent in the form of particles, so that at the time of color formation, the inter layer is melted to remove the color developed in the first layer and, at the same time, to make the second layer visible. In the colored layer, it is ideal to use a pigment or dye having a color which is complementary to the color to be developed in the first layer. Further, when the binder used is a water-soluble polymer, not only the binder is easily applicable to the paper surface, but also the production cost of recording paper can advantageously be reduced.

Examples of the pigment or dye to be used in the colored layer include carbon black (black), Benzidine Yellow (yellow), Chrome Vermilion (orange), Lake Red C (red), Toluidine Red (red), Phthalocyanine Blue (blue), Phthalocyanine green (green), Methyl Violet, Methylene Blue, Auramine O, Fuchsine NB, Congo Red and Acid Violet.

Evaluation method for investigating the effect of the present invention is as mentioned below.

A heat-sensitive recording sheet is colored for decolored by means of a metal stamp bed capable of being maintained at a definite temperature, and the colored or decolored image is represented by a reflective optical density (hereinafter referred to as R.O.D.), whereby a relative comparison can conveniently be made. In the evaluation according to the present invention, the recording was effected by use of a column-shaped stainless steel-made stamp having an end diameter of mm. which had a heating portion in the interior, and a thermal head having silicon oxide film resistors as 10 heat-generating members, and the ROD. was measured by means of Automatic Equilibrium Densitometer NLM VI manufactured by Narumi Co. and Microdensitometer manufactured by Konishiroku Co. The filter used was a gelatin filter produced by Kodak Co.

Referential Example 1 200 Parts by weight of an aqueous solution containing 10% by weight of a polyvinyl alcohol (PVA 205 produced by Kurare Co.) was mixed with 35 parts by weight of 3,3-bis(p-dimethylaminophenyl) G-dimethylaminophthalide as a color-forming dye, and the resulting mixture was pulverized in a ball mill for more than 1 hour to obtain a dispersion (hereinafter referred to as liquid A). In the liquid A, the color-forming dye had scarcely dissolved and had been dispersed in the form of fine particles of less than 5 microns.

On the other hand, 200 parts by weight of an aqueous solution containing 10% by Weight of polyvinyl alcohol was mixed with 35 parts by weight of bisphenol A as a color-forming agent, and the resulting mixture was pulverized in a ball mill for more than 1 hour to prepare a liquid B. In the liquid B, the color-forming agent had been dispersed in the form of fine particles of less than 5 microns.

Subsequently, 1 part by weight of the liquid A was mixed with 20 parts by weight of the liquid B by use of a homogenizing mixer. In the mixed liquid comprisng the liquids A and B, the color-forming dye and the colorforming agent had individually been dispersed as fine particles and had individually been surrounded by the polyvinyl alcohol, so that it may be said that there was no direct contact between the two particles. The thus obtained mixed liquid was coated by use of a wire bar on a white paper of 70 g./m. air-dried and then dried at a temperature of 40 to 45 C., on a photographic ferro plate to prepare a heat-sensitive one color recording paper. The amount of the coated mixture after drying was 5 g./m. The thus prepared recording paper had such a construction as shown in FIG. 4. The recording paper was colored by means of a stamp type color tester, whereby a clear blue image was obtained. When stamp temperatures are plotted on a horizontal axis and R.O.D. values on a vertical axis, there is obtained a curve corresponding to the H-D curve (characteristic curve) which is generally used in the photography. The temperature giving an R.O.D. of fog (D +0.1 is referred to as color forming sensitivity and is represented by Ts In this example, the said temperature Ts was C, the maximum density D max was 1.35, and the ROD. of fog (D;) was 0.04 (refer to FIG. 6).

The recorded image thus obtained was sufficiently visible even when allowed to stand in a room for 6 months.

Referential Example 2 A recording sheet of the construction as shown in FIG. 5:

In this case also, the same liquids A and B as in Referential Example 1 were used. In addition to said liquids, however, a liquid C was prepared by dissolving 10 parts by weight of polyethylene glycol (#6,000, produced by Nippon Yushi Co.) in parts by weight of water.

The liquid C was coated by means of a wire bar on a white paper of 70 g./m. air-dried and then dried at a temperature of 40 to 45 C. by use of a photographic ferro plate to form a layer on the paper. Subsequently, the same mixed liquid comprising the liquids A and B as in Referential Example 1 was coated by means of a wire bar on the abovementioned layer, air-dried and then dried at 40 to 45 C. by use of a photographic ferro plate to prepare a recording sheet. The thus prepared recording sheet was recorded by means of a thermal recorder using a silicon oxide film resistor. The recording was effected at a pen speed of 300 mm./ sec. and the measurement of R.O.-D. was conducted by use of Microrepresented by T and the ROD. value at that time was represented by D TABLE 1 First heat-sensitive recording material Decolorization layer Characteristics Referential example Color forming Decolorizing I Tsi T number Color-forming dye agent Binding agent Liquld 0.) C.) Dm Durex-1 Dfr Color 3-1 3,3-bis(p-dirnethyl- Ohloroglyeine Hydroxyethyl Polyethylene C-2 60 110 0.12 1.13 0.00 Bluish aminophenyl)-6- carboxylie cellulose. glycol. purple. dimethylamino acid. phthalide.

3-2 3,6-dimethylfluoran.- 2,2-Di Polyvinyl Polyoxy- C-2 63 110 0.08 0.60 0.02 Red.

hydroxy alcohol. ethylene diphenyl. oleyl ether.

3-3 9-pn.itroanilino-3,6- Gallic acid Styrene- Polyethylene C-1 105 130 0.09 0.75 0.06 Blue.

bis(diethylamino)-9- butadiene glycol. xanthenyl-o-benzoic copolymer. acid lactam.

3-4 3,3-bis(p-dimethylfi-Naphthol.-- Gelatin Sorbitan C-2 67 110 0.09 0.90 0. 07 Bluish aminophenyl) monogreen. phthalide. stearate.

3-5 3,7-bis(diethylamino)- Methyl-l- Starch Polyoxy- C-2 65 120 0.25 0.98 0.11 Black.

fluoran. hydroxyethylene benzoate. sorbitan mono-oleate.

3-6 S-dimethylaminop-Hydroxy- Polyvinyl Polyethylene C-1 90 130 0.07 0.70 0.03 Red.

phenyl-5,7-dimethylbenzoic alcohol. glycol fiuoran. acid. monostearate.

3-7 3,3-bis(p-dimethyl- 4,4isoprod Polyethylene C-2 87 115 0.10 1.25 0.06 Bluish aminophenyD-fipylidene glycol. purple. dimethylamino pylidene phthalide. dipehnol.

densitometer manufactured by Konishiroku Co. As the result, a blue color initiated to develop at an energy of 1.5 mi. (milli-joules), reached maximum (D-max=0.6) at 2.0 mj., gradually disappeared thereafter, and completely disappeared at 3.0 mi. (refer to FIG. 7).

'Referential Example 3 Another embodiment of recording sheets prepared by using other combinations of color-forming dyes and color-forming agents, binders and decolorizing agents:

Liquids A and B corresponding to those in Referential Example 1 were prepared by use of the components shown below.

Liquid A: Parts by weight 10% Binder solution 200 Color-forming dye 35 Liquid B:

10% Binder solution 200 Color-forming agent 35 These liquids were individually pulverized and dispersed by means of a ball mill for more than 1 hour, and

' g were mixed with each other immediately before use by means of a homogenizing mixer. The mixing ratio of liquid A to liquid B was 1:20 by weight.

0n the other hand, liquids C-1 and C2. were prepared by use of the components shown below.

The liquid C-2 was prepared by pulverizing in a ball mill for more than 1 hour a mixture comprising parts by weight of a polystyrene (Picolastic D 150, produced by 'Esso Standard Oil Co.), 70 parts by weight of a 1:1 mixed solution of toluene and benzene, and 20 parts by weight of a decolorizing agent. The above-mentioned 3 kinds of liquids were individually coated on a coating paper of 70 g./m. and then dried to prepare a heatsensitive recording paper. Thereafter, the thus prepared recording paper was colored or decolored by use of a stamp type color-forming tester to measure such characteristics as mentioned in Referential Example 1.

The results obtained were as set forth in Table 1, in which the temperature for complete decolorization was Procedure for preparing only the second heat-sensitive recording material by use of an electron donor and an electron acceptor:

500 Parts by weight of a toluene-methanol mixed solution containing 20% by weight of polyvinyl butyral is equally divided into two to prepare liquids D and E. The liquid D is mixed with 25 parts by weight of an electron donor, and the liquid E is mixed with 25 parts by weight of an electron acceptor, and the resulting mixtures are individually pulverized by means of a ball mill for at least 2 hours. The thus prepared electron donor dispersion and electron acceptor dispersion are mixed with each other in a weight ratio of 1:1.

Referential Example 4 According to the above-mentioned procedure, liquids D and B were prepared by using ferric stearate as the electron acceptor and gallic acid as the electron donor. The two liquids were mixed with each other in a ratio of 1:1, and the resulting mixture was coated on a paper and sufficiently dried to obtain a recording paper. The thus obtained recording paper was colored by means of the stamp type color tester used in Referential Example 1, whereby a deep black color was obtained. The color formation sensitive curve of the recording paper was as shown in FIG. 8.

Example 1 A second color layer-forming material containing cadminium stearate as an electron donor and diphenylcarbazone as an electron acceptor was coated on a high quality paper of microns in thickness, and then gradually dried at about 80 C. to form a second color layer on the paper. Thereafter, an inter layer-forming material containing polyethylene glycol was coated on the above-mentioned layer and then dried to form an inter layer. Subsequently, the mixed liquid prepared in Referential Example 1 was coated on the inter layer and then gradually dried to obtain a recording paper. The weights of the first color layer, the inter layer and the second color layer were 2 g./m. 0.2 g./m. and 5 g./m. respectively.

The thus obtained recording paper was recorded by means of a recorder using a thermal head, whereby the first layer formed a blue color when thermal head temperature was to C., and the second layer formed a red color when the thermal head temperature became more than 125 C. More particularly, the blue color was formed at 85 to 90 C. and completely disappeared at to C., and only the red color of the second layer 13 was formed at above 125 C. Subsequently, the two color recording paper was subjected to recording by means of a thermal printer using silicon oxide film resistors, whereby a blue color was formed at an imput energy of 7 mj./dot. The thus formed blue and red colors were sufiiciently Example 10 Diphenylcarbazole as an electron acceptor, cadmium stearate as an electron donor and polypropylene glycol as a decolorizing agent were treated in the same manner as bl to Storage. in Example 9 to prepare a liquid. This liquid was coated Example 2 on the same paper as in Example 9 and then sufiiciently dried to form a layer on the paper. Subsequently, a liquid A recordmg Paper was P' In same manner containing Leuco Crystal Violet as a color-forming dye as Example 3 except that 3dlmethylammo'sfl'dlmefh' and bisphenol A as a color-forming agent was coated on ylfluoran and blsphenol A were used as the colorfonmng the above-mentioned layer and then sufficiently dried to comlmnents of the first f Polypropylene glycol f obtain a recording paper. The thus obtained recording used as dthe inter layer material, and ferric stearate, galhc paper was Subjected to recording by use of a 2 pen type acid an titanium oxide were used as the color-forming thermal recorder, which had been so designed that a components of the second layer. ThlS recording paper was definite energy could always be applied to the paper by Subjected to recording by use of thermal head kept at 95 use of silicon oxide film resistors. As the result, a brilliant 130 whereby a m red P was formed blue color was recorded on the first low energy side and a at i black color mlgrated wlth no red color brilliant red color was recorded on the high energy side. was orme at O Further, when the said recorded was operated at a speed Examples 3-8 of 2 cm./hr. to 300 mm./sec., definite red and blue colors Recording papers were prepared in the same manner as Could always be recorded in Example 1, except that the components of individual Example 11 layers were as shown in Table 2, and were sub ected to the same recording as in Example 1. The results obtained Combinations of second layer-constituting materials were as set forth in Table 2. comprising several diazo components:

TABLE 2 Developed colors Example Color-forming components of Decolorizing agent of the Color-forming components of the number the first layer inter layer second layer Fist layer Second layer 3 Cristal violet lactone bisphenol Sorbltan monostearate Ferric stearate gallic acid Blue Black. 4 do Pclyoxyethylene oleyl ether. Nickel acetate calcium sulfide do Do. 5 3-dimethylamino-5 7-dimethyl- Polyethylene glycol Ferric stearate octadecly ferrocyanide Red Blue.

fluoran 4-hydroxybenzoate. 8 do Polyethylene glycol mono- Cesium stearate 4-methoxy-l-hydroxy do Do.

stearate. diphen 7 Cxgstal violet lactone bisphenol Polyethylene glycol Silver hehenate procatechuic acid Blue Red. 8 (in Polypropylene glycol N-Dodecylthiourea guanidyl carbonate do Black.

lead p-toluene-sultonate.

Example 9 Liquid F: Parts by weight 200 Parts by weight of a 1:1 mixed liquid of the liquids 6 59 523; gig g' 3 D and E prepared in Referential Example 4 was mixed Llqllld G. with 50 parts by weight of a l1qu1d prepared by dispersing Diazo coupler 15 10 parts by weight of polyethylene glycol in 100 parts by 10% Binder Solution 100 weight of toluene, and the resulting mixed liquid was sufficiently stirred. This liquid was coated on a high quality Each of liquids F and G of the above compositions were paper of 80 microns in thickness in a proportion of 7 individually pulverized for more than 10 hours by means g./m. and then dried to form a layer on said paper. On of a ball mill having an inner volume of 200 ml. to the other hand, a liquid was prepared in the same manner form dispersions. The size of each dispersed particle after as in Referential Example 1 by use of 1,3,6-bis-fl-meththe pulverization was 0.1 to 5 microns. Each 100 parts by oxyethoxyfluoran as a color-forming dye and bis-phenol Weight of the dispersions were mixed with each other by A as a color-forming agent. This liquid was coated on the means of a homogenizing mixer. Subsequently, the mixed above-mentioned layer in a proportion of 2 g./m. sufdispersion was coated on a paper, air-dried and then dried ficiently dried and then finished by use of a calender roll by use of a photographic ferro bed to prepare a recordto prepare a recording paper. The thus prepared recording mg material. The amount of the dispersion coated was 3.5 paper was subjected to recording by use of a head made to 10 g./m. The thus prepared recording paper was of silicon oxide film resistors arranged in one line in the tested by use of a stamp type color forming tester. The horizontal direction and 7 lines in the vertical direction. results obtained were as set forth in Table 3.

TABLE 3 Second layer-constituting materials Characteristics 'ISz Developed Example number Diazo compound Azo coupler Binder C.) D- Df color 11-1 l-tgiaga -iz methy1-4-chlorobenzene- 1,8,5-hydroxybenzene Ethyl cel1ulose.... 125 0.76 0.07 Rcddislh L11 6. 11-2 4-ch l ord-2-nitroaniline 3-hydroxy-2-naphthol-0- Ethylene-buta- 107 0.65 0.05 'Igrkigh red.

toluidide. dlene copolymer. 11-3 4-eihloro-2,2-trichloromethy1 aniline 3-hydroxy-2-naphthanilide.. Polystyrene 127 0.85 0.08 Red.

1 0111 11-4 4-ar i nc-3 fitroanisole hydrochloride 3-hydroxy-2-naphth0-0- d0 123 0.98 0.13 Bordeaux.

% ZnClz. anilide.

When the speed was 45 characters/sec, a brillant red color was recorded at an energy of 6 mj./ dot and a brilliant black color was recorded at an energy of 10 mg./ dot. The thus obtained record could be stored stably without any change.

In Table 3, Ts is a color forming sensitivity. D- is a maximum density, and Df is a fog density.

Several examples concerning the constructions of heatsensitive two color recording sheets are mentioned below. These are the constructions shown in FIGS. 1 and 2, and, in practice, there may be thought out many combinations by varying the coating order.

Example 12 A recording sheet was prepared b use of the materials described in Example 11-1, and polyethylene glycol dispersed in a toluene solution of polystyrene was coated 1 6 Example 14 Recording sheets of the construction shown in FIG. 1: Using such components as in Table 4, heat-sensitive two color recording sheets were prepared in the same thereon in a proportion of 2 g./m. to form a layer 5 manner as in Example 12. The characteristics of the on the sheet. Subsequently, a color-forming component recording sheets were as set forth in Table 4.

TABLE 4 Characteristics Example Decolorlzing 'Isr Tor Ts:

number First layer agent Second layer C.) 0.) C.) Durex-1 Dmx-r Di First color Second color 3,3-bis(p-dlmethyl- 4-chloro-2- aminophenyD-tihitroaniline. dimethylamino Sorbitan 3-hydroxy-2- 14-1 phthalide. mononaphthol-O- 67 110 107 0.88 0.63 0.09 Bluish Turkish fl-Naphthol. stearate. toluidide. green. red. Styrene-butadlene Ethylenecopolymer. bntadiene copolymer. 4-amino% nitroanlsole 3,6-dlmethylfluoran. Polyoxyhydrochloride- 14-2 2,2-dihydroxyethylene kZnClz. 63 108 125 0.61 0.90 0.15 Red Bordeaux.

diphenyl. oleyl ether. 3-hydroxy-2- Polyvinyl alcohol. naphtho- O-anilide. Polystyrene. 3,3-bis(p-dimethyl- 4-chloro-2,2- amlnophenyD-G- trichlorodlmethylamino Polymethylanillne 14-3 phthalide. ethylene diazonium. 85 115 130 1. 0.80 0.10 Bluish Reddish 4,4'-isopropylidene glycol. 3-hydroxy-2- purple. orange.

dipheno naphtho-O- Polyvinyl alcohol. anilide.

Polystyrene. 14-4 do Polyethylene ..do 86 115 130 1.15 0.72 0.15 -do Do.

glycol mopostearate. 14-5 3-dlmethylarnino- 1-diazo-2-methylphenyl-5,7-dl- Polyproi-chloro- 90 130 125 0.65 0.75 0.13 Red Brownlsh methylfluoran. pylene benzene% purple. 14-5 p.Hydroxybenzo1c glycol. Zn 2- acld. 1,3,5-hydroxybenzene. Polyvinyl alcohoL. Ethyl cellulose.

COIIlPllSlIlg Crystal Violet Lactone and 2,2-d1hydroxyd1- Example 15 phenyl was coated on the above-mentioned layer in a proportion of 2.5 g./m. to prepare a heat-sensitive two color 4 recording sheet. This recording sheet was tested in characteristics by means of a stamp type color forming tester to obtain the results shown below.

(Df is the fog density of un-colored portion of the record* ing sheet.)

The color of the first recording material was a brilliant bluish purple color (a cobalt color), and that of the second recording material was a reddish orange color.

Example 13 Recording sheet of the construction (FIG. 2) comprising a first recording material and a second recording material incorporated with a decolorizing agent:

15 Parts by weight of polyethylene glycol was added to each of the liquids -F and G used in Example 11-1, and the resulting mixture was pulverized for more than 10 hours by means of a ball mill having an inner volume of 200 ml. The size of each dispersed particle was 0.1 to 5 microns. After the pulverization, each 50 parts by weight of the liquids F and G were quickly mixed with each other by means of a homogenizing mixer, and the resulting mixed liquid was coated on a paper of 70 g./m. airdried and then dried by use of a ferro bed to form a layer. Subsequently, an equal amount of the first color-forming component of Example 12 was coated on said layer, and then air-dried to prepare a recording sheet. The thus prepared recording sheet was investigated in characteristics by means of a stamp type color forming tester to obtain entirely the same results as in Example 12.

In the same manner as in Referential Example 1, an

a color-forming dye and p-hydroxybenzoic acid as a colorforming agent. The emulsion was coated on a white paper of g./m. and then dried to form a layer on the paper. The amount of the coated emulsion after drying was 7 g./m. The thus coated paper was subjected to a calender roll to make the surface thereof sufliciently smooth, and then the liquid C-2 used in Referential Example 2 was coated on the paper surface and then dried to form a layer thereon. The amount of the coated liquid after drying was 0.42 g./m. 0n the otherhand, an emulsion was prepared in the same manner as in Referential Example 1 by use of Crystal Violet Lactone as a color-forming dye and'bisphenol A as a color-forming agent. This emulsion was coated on the above-mentioned layer and then dried to obtain a recording paper. The amount of the coated emulsion after drying was 1 g./m.

The thus obtained recording paper was subjected to recording by use of a thermal recorder having silicon oxide films resisters as heat-generating members and under a speed condition of 200 m./sec., whereby a blue color could be recorded at 1.5 mi. and a red color at 2.5 mi. Subsequently, the first and second colors were measured in reflective optical density by means of Konishiroku Microdensitometer using a filter. The results obtained were shown in Fig. 9, wherein the vertical axis shows the reflective optical density, and the horizontal axis shows the width of line.

Fig. 9-(A) is a graph showing the reflective optical densities of the first color formed at 1.5 mj., in which the solid line 1 represents the reflective optical densities of the first color when measured by use of a red filter (Ratten No. 25 produced by Kodak Co.), and the dotted line 2 represents those of a red color component detected in a more or less amount in the first color when measured by use of a blue filter (Ratten No. 55 produced by Kodak Co.). Visually,

1 7 the first color is a substantially complete blue color, though a more or less amount of red color was detected by the densitometer.

Fig. 9-(B) is a graph showing the reflective optical densities of the second color formed at 2.5 mj., in which the 18 The above-mentioned black coating layer was formed by coating on the paper a mixture of 100 parts by weight of an aqueous solution containing 4% by weight of polyvinyl alcohol and 10 parts by weight of carbon black. The polyvinyl alcohol acted as a binder for the pigment solid line 3 represents the reflective optical densities of particles. The thickness of the black coating layer was the second color when measured by use of the abovemade about 2 microns. mentioned blue filter, and the dotted l ne 4 represents The above-mentioned opaque light-scattering particle those of a blue color component detected in a more or less layer of a fusible material was formed in such a manner amount in the second color when measured by use of the that 30 parts by weight of polyethylene glycol (average above-mentioned red filter. Visually, the second color is molecular weight 7,000) and 100 parts by weight of a a s bs anti lly brllllflnt red color, though a more r 1 solution comprising acetone and toluene in a volume ratio amount of blue color was detected by the densitometer on f 1:1 were mixed i h 25 parts weight f a 1 wt both sides of the recorded Curve f t red 001011 percent solution of nitrocellulose in a 1:1 mixed solvent In the above manner, two blllllant Could be of acetone and toluene, and the resulting mixture was recorded. The thus recorded colors were sufficiently stable coated on the above-memioned black layer and then to Storagesufliciently dried with hot air at below 50 C. The thicklfurther, th ah v recordmg pap r ness of the light-scattering particle layer was about 3 sub ected to recording by use of a head comprising s1l1con i Qxlde film reslstors of 7 dots and under a Speed eondl- The black color of the aforesaid black layer had been tron of characters/sec, whereby a blue color could be protected substantially completely with the said lightrecorded at 6 1- and a brllllant red 00101 at 10 scattering particle layer, and hence was not visible.

Example 16 The thus obtained recording paper was subjected to recording at a speed of rum/sec. by means of the 011251 P p Were sueceeslvely coated 1n thls e 5 5 aforesaid recorder using silicon oxide film resistors, a Second color-formmg component eompl'lsmg whereby a black color could be recorded at an input engallic acid and Leuco Crystal Violet Lactone, 0.3 g./m. ergy f L3 0f the deeolerlllng agent e 111 Example 15, 1 Further, the recording paper was tested in color forof a first eolor-developlng eomponent eompflsmg mation by use of the aforesaid stamp type color form- 9 'd1hydr0xybe11z0ate and P l f 30 ing tester, whereby a black color initiated to develop at quently, the coated paper was sufficlently dried to obtain and reached the maximum. density at MOre a feeofdlng P p T1115 l'eceldmg P p sllbleeted to particularly, the opaque layer initiated to be made transrecol'dmg by e f the same recorder as Example parent at 75 C. and was completely made transparent at whereby tWQ bl'lnlant fed and blue Colors could be 90 C. to make the lower colored layer visible. In this corded as the first and Second colors, respectively 35 case, the fog density (density prior to recording) was Example 17 1 Example 19 Recording papers were prepared in the same manner as in Example 15, and then subjected to recording at a 5 Parts by weight of fuchsine was dissolved in speed of 60 mm./sec., using silicon oxide film resistors. 40 parts by weight of water. 10 Parts by weight of the re- The results obtained were as set forth in Table 5, in sulting solution was mixed with 30 parts by weight of a which the color formation temperatures are temperatures 4% aqueous polyvinyl alcohol solution, and the mixed of the heating portions of the silicon oxide film resistors. solution was coated on a base paper to form a colored TABLE 5 Ratio in 81110111112 0f color-forming Color formation components temperatures and colors Example Color-forming components Dccolorizing agent Color-forming components First: Second First Second number of the first layer of the inter layer of the second layer layer layer layer layer 171 Leuco crystal violet lactone, Polyoxyethylene Rhodami fl 0 m, 117

B-naphthol. alkylamide. p-hydroxybenzoic acid. 17- Leuco crystal violet lactone, do do 1: .d0 D0.

2,2-dihydroxydiphenyl. o a 17- Leg colrlirystlaiviolet lactone, Polyethylene glycol d0 115 blue" 215 17-4 Rh o arg i e lactam, bisphenol Polyoxyethylene Leuco crystal violet, 1:8 140 0., red-.. 230 0., blue.

A. alkylallyl ether. lactone, gallic acid. 17- .do Polyethylene glycol ..d0 1:7 do 225 (3., blue. 17-6 do Polyoxymethylene .do 1:10 do 220 0., blue. 17-7 Leuco crystal violet lactone, do Rhodaminelactam, p- 1:10 135 0., blue 215 0., red.

bisphenol A. hydroxybenzoie acid.

Two brilliant colors could be recorded also on a 60 layer. On the other hand, 30 parts by weight of polyrecording paper prepared by successively coating on a base paper in this order (i) a previously colored dye or pigment and a binder, (ii) polyether and polyethylene glycol derivatives dispersed as light-scattering particles into a thermoplastic polymer capable of forming by itself a transparent thin layer, and (iii) a color-forming substance comprising a leuco dye base of the triphenylmethane type, a dye of the fluoran type and a phenolic substance.

Example 18 Onto a continuous sheet-like paper of 75 microns in thickness were successively formed a black sub-coating layer and an opaque light-scattering particle layer (inter layer) of an inherently fusible material.

propylene glycol, 10 parts by weight of nitrocellulose, 30 parts by weight of hydrogenated fatty oil wax and 10 parts by weight of talc were added to parts by weight of a mixed solution of acetone and toluene, and the resulting mixture was kneaded by means of a ball mill to form a dispersion. 10 Parts by weight of this dispersion was mixed with 10 parts by weight of a 1:1 mixed solution of acetone and toluene, and then coated on the surface of the aforesaid colored layer to form an opaque light-scattering layer. The thickness of the light-scattering layer after thorough drying was 4 microns. Subsequently, a color-forming component comprising Leuco Crystal Violet Lactone as a color-forming dye and 2,2'-dihydroxydiphenyl as a color-forming agent was coated on the above-mentioned light-scattering layer. The thus coated paper was dried to prepare a recording paper. This recording paper was subjected to recording at a pen speed of 60 mm./sec. by use of a recorder having silicon oxide film resistors as heat-generating members. The first color, i.e. blue color, was formed at a thermal head temperature 6. A heat-sensitive two color recording paper according to Claim 1, wherein the polyether has been dispersed in the second layer. a

' 7. A heat-sensitive two color recording paper according to Claim 5, wherein the second layer is a previously of 120 C. and disappeared at 150 C., and, at the same colored layer, and the inter layer has been so constructed time, a red color initiated to be made visible and reached as to act as a protective layer for the second layer so that, the maXlmllm dens ty at 200 C. These two colors were by application of heat, the inter layer becomes substanbrilliant colors which had not been migrated with each i ll transparent to k h second 1 i ibl other; Of es colors, the fi color somewhat 8. A heat-sensitive two color recording paper accordlow 111 S tab1htY- However, a fi 9 Whlch had ing to Claim 5, wherein the second layer is a layer comforfned recordmg matenal havmg a Fhermoplastlc posed of a triphenylrnethane or fluoran type non-colored i i disposed tw i? h layer and dye base having in the molecule a reactive color-forming t e rst ayer was quite exce em Sta llty' component of the lactam or lactone ty e and of a henolic n o p Example 20 acid substance or an organic acid which have been dis- Using such components and materials as shown in persed as discontinuous particles in the film-forming Table 6, two color recording papers were prepared in the l the amount of f colorformmg f same manner as in Example 19. According to the procebemg at 5 Parts by Welght Per P by Welght of the dure described in Example 19, the recording papers were color'formmg subsiance of the first layer; measured in color formation temperatures and colors of 20 9. In a heat-sensitive two color recording paper of two the second and first layers. The results obtained were as layers which individually develop difierent colors due to a set forth in Table 6. difference in the quality of heat applied to the paper sur- TABLE 6 Inter layer-constituting materials Color formation Qoloring temperatures and colors Example Color-forming components Decolorizing pigment of the number of the first layer Binder agent Additives second layer First layer Second layer 20-1 Leuco crystal violet lactone, Nltro- Polyethylene Talc Lake red 0 102 0., blue 150 0., red.

2,2-methylenebls(4- cellulose. gly col chlorophenol) 20- Leuco crystal violet lactone, Ethyl Polyethylene Talc, hydro- Carbon black 108 0., blue 145 0.,

bisphenol A. cellulose. glycol genated fatty black.

monostearate. oil wax. 20-3 Rhodamlnelactam, Styrene Polyoxyethylene ....do Phthalocyanine 100 0., red.-- 145 0.,

bisphenol A. polymer. alllrlylallyl blue. blue.

6 81. 204 Rhodamine lactam, 4- Nitro- Polyethylene -....do Carbon black"... 90 0., rcd 140 0., hydroxyacetophenone. cellulose. glycol. black.

What is claimed is:

1. A heat-sensitive two color recording paper which has a layer of a first heat-sensitive recording material prepared by dispersing, as discontinuous particles into a filmforming binder, a triphenylmethane or fluoran type noncolored dye base having in the molecule a reactive colordeveloping component of the lactone or lactam type, and a phenolic substance or an organic acid, said layer developing a color at the time of application of heat, by formation of a color-developing substance, and a layer of a second heat-sensitive recording material capable of developing at the time of application of heat a color different from the color of the aforesaid first layer, and which contains as a decolorizing agent for the color-developing substance contained in the first layer a thermofusible polyether which is substantially solid at normal temperature.

2. A heat-sensitive two color recording paper according to Claim 1, wherein the quantity of heat A necessary to develop the color of the first layer, the quantity of heat B necessary to form the color of the second layer, and the quantity of heat C necessary to fluidize the thermofusible polyether are in such a relation as to satisfy the inequality A CB.

3. A heat-sensitive two color recording paper according to Claim 1, wherein the second layer has such a construction that an electron donor and an electron acceptor have been used as color-forming components and have been dispersed as discontinuous particles into the film-forming binder.

4. A heat-sensitive two color recording paper according to Claim 1, wherein the second layer has such a construction that a diazo compound and an azo coupler have been used as color-forming components and have been dispersed as discontinuous particles into the film-forming binder.

V 5. A heat-sensitive two color recording paper according to Claim 1, wherein the polyether has been dispersed in the film-forming binder and disposed as an inter layer between the first layer and the second l yer.

face and which has a layer of a first heat-sensitive recording material prepared by dispersing, as discontinuous particles into a film-forming binder, a. triphenylmethane or fluoran-type non-colored dye base having in the molecule a reactive color-developing component of the lactone or lactam type, and a phenolic substance or an organic acid, said layer developing a color at the time of application of heat, and a layer of a second heat-sensitive recording material capable of developing at the time of application of heat a color diiferent from the color of the aforesaid first layer, the improvement which comprises employing in said recording paper a decolorizing agent for the color-developing substance formed in the first layer a thermofusible polyether which is substantially solid at normal temperature.

10. The heat-sensitive two color recording paper of claim 9 wherein said triphenylmethane or fluoran type non-colored dye base is selected from the group consisting of 3,3-bis(p-dimethylaminophenyl) -phthalide,

3 ,3-bis (p-dimethylaminophenyl) -6-dimethylaminophthalide,

3, 3 -bis p-dimethylaminophenyl) -6-nitrophthalide,

3,3-bis (p-dimethylaminophenyl -6-monomethylaminophthalide,

3,3-bis (p-dimethylarninophenyl -6-chlorophthalide,

3,3-bis (p-dimethylaminophenyl -6-ethoxyphthalide,

3,3-bis (p-dimethylaminophenyl) -6-diethylaminophthalide,

3-dimethylamino-6-methoxyfiuoran,

7-acetamino-3-dimethylaminofluoran,

3-dimethylamino-S,7-dimethylfluoran, 3-diethylamino-5,7-dimethylfluoran, 3,6-bis-fi-methoxyethoxyfluoran, 3,G-bis-fl-cyanoethoxyfluoran,

9-p-nitroanilino-3,6-bis(diethylamino)-9-xanthenyl-6- benzoic acid lactam, and

9-nitroamino-3,6-bis (dimethylamino) -9-thioxanthenyl- 6-bei1zoic acid lactam.

the group consisting of 4-tert-butylphenol, 4-phenylpheno1, 4-hydroxydiphenoxide, a-naphthol, methyl-4-hydroxybenzoate, fl-naphthol, 4-hydroxyacetophenone, 4-tert-octyl catechol, 2,2-dihydroxydiphenyl, 2,2-methylenebis 4-chlorophenol) 4,4'-isopropylidene diphenol, 4,4-isopropylidenebis (2-chlorophenol) 4,4-isopropylidenebis (2,6dibromophenol) 4,4-isopropylidenebis 2,6-dichlorophenol) 4,4'-isopropylidenebis (Z-methylphenol) 4,4'-sec-isobutylidene diphenol, 4,4'-cyclohexylidene diphenol, 2,2'-thi0bis (4,6-dichlorophenol hydroquinone, pyrogallol, phloroglucine, and phloroglucinolcarboxylic acid.

12. The heat-sensitive two color recording paper of claim 9 wherein said phenolic substance is selected from 22 tartaric acid, oxalic acid, maleic acid, citric acid, succinic acid, gallic acid, l-hydroxy-Z-naphthenic acid, and 2-hydroxy-p-toluyl acid. 13. The heat-sensitive two color recording paper of 10 claim 9 wherein said thermofusible polyether is selected claim 9 wherein said organic acid is selected from the from the group consisting of polyethylene glycol,

polyethylene oleyl ether,

sorbitan monostearate, polyoxyethylene sorbitan mono-oleate, polyethylene glycol monostearate, polypropylene glycol, polyoxyethylene alkylamide, polyoxyethylene alkylamine, polyoxyethylene alkylallyl ether, and polyoxymethylene.

References Cited UNITED STATES PATENTS 9/1972 Desjarlais 117-369 RALPH HUSACK, Primary Examiner US. Cl. X.R. 

1. A HEAT-SENSITIVE TWO COLOR RECORDING PAPER WHICH HAS A LAYER OF A FIRST HEAT-SENSITIVE RECORDING MATERIAL PREPARED BY DISPERSING, AS DISCONTINUOUS PARTICLES INTO A FILMFORMING BINDER, A TRIPHENYLMETHANE OR FLUORAN TYPE NONCOLORED DYE BASE HAVING IN THE MOLECULE A REACTIVE COLORDEVELOPING COMPONENT OF THE LACTONE OR LACTAM TYPE, AND A PHENOLIC SUBSTANCE OR AN ORGANIC ACID, SAID LAYER DEVELOPING A COLOR AT THE TIME OF APPLICATION OF HEAT, BY FORMATION OF A COLOR-DEVELOPING SUBSTANCE, AND A LAYER OF A SECOND HEAT-SENSITIVE RECORDING MATERIAL CA VELOPING AT THE SAME TIME OF APPLICATION OF HEAT A COLOR DIFFERENT FROM THE COLOR OF THE AFORESAID FIRST LAYER, AND WHICH CONTAINS AS A DECOLORIZING AGENT FOR THE COLOR-DEVELOPING SUBSTANCE CONTAINED IN THE FIRST LAYER A THERMOFUSIBLE POLYETHER WHICH IS SUBSTANTIALLY SOLID AT NORMAL TEMPERATURE. 